Kinetics and Mechanism of Chlorination of N-Acetylglycin by Chloramine-T In Acidic Medium

نویسندگان

چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kinetics and Mechanistic Study of Oxidation of Amoxicillin by Chloramine-t in Acid Medium

This spectroscopic study presents the kinetics and degradation pathways of oxidation of amoxicillin (AMOX) by chloramines-T (CAT) in acidic medium at a constant ionic strength of 0.105 mol dm-3 at 298 K. Reaction between AMOX and CAT in acidic medium exhibits 1:1 stoichiometry (AMOX:CAT). The reaction is of a first-order in both [CAT] and [AMOX]. The order with respect to acid concentration was...

متن کامل

Kinetics of Oxidation of Indigo Carmine by N-Sodio-N- Bromotoluenesulfonamide in Acidic Buffer Medium

The kinetics of oxidation of indigo carmine (IC) by N-sodio-N-bromotoluenesulfonamide or bromamine-T (BAT) in pH 5 buffer medium has been investigated at 30°C using spectrophotometry at 610 nm. The reaction rate shows dependencies of first-order on [IC] 0 , second-order on [BAT]0, fractional order on [H 1], and inverse first-order on [p-toluenesulfonamide]. The addition of chloride and bromide ...

متن کامل

Kinetics and Mechanism of Oxidation of n-Pentanol by Tetramethylammonium Fluorochromate

The oxidation of n-pentanol by tetramethylammonium fluorochromate in acidic solution wasstudied using spectrophotometric technique. The reaction was arranged to be under pseudo firstorderconditions respect to the oxidant. A Michaelis-Menten type kinetic was observed respect tothe substrate. The reaction is catalyzed by hydrogen ions. Dependences of the reaction rates ontemperature and different...

متن کامل

Kinetics and mechanism of oxidation of semicarbazide by Keggin type 12-tungstocobaltate(III) in acidic medium

The kinetics of oxidation of semicarbazide by 12-tungstocobaltate (III) in aquous acidic medium at 300K and a constant ionic strength of 0.3 mol dm was studied spectrophotometrically at λmax 624nm under pseudo first-order conditions. The reaction between semicarbazide and 12-tungstocobaltate (III) in acidic medium exhibits 1:2 stiochiometry [Semicarbazide:12-tungstocobaltate (III)]. The main ox...

متن کامل

Kinetics and mechanism of oxidation of D-mannitol by potassium bromate in aqueous acidic medium

Kinetic investigation in Rh(III) catalyzed oxidation of D-Mannitol in an acidified solution of potassium bromate in the presence of Hg(OAc)2 as a scavenger, have been studied in the temperature range of 30 45 C. Increase in concentration of oxidant and H ion showed fractional positive order and fractional inverse order respectively. The influence of Hg(OAc)2, ionic strength and Cl ion on the ra...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: JOURNAL OF EDUCATION AND SCIENCE

سال: 1999

ISSN: 2664-2530

DOI: 10.33899/edusj.1999.58805